Chemistry Alcohols & Phenols MDCAT 2017
PMDC Verified Question 75 of 95
\(\text{C}_2\text{H}_5-\text{SO}_4\text{H} \xrightarrow[\text{Warm}]{\text{H}_2\text{O}} \text{C}_2\text{H}_5-\text{OH} + \text{H}_2\text{SO}_4\) choose the correct type for this reaction from the following?
A
Reduction
B
Hydroxylation
C
Oxidation
D
Hydration
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Hydration
Concept:

The reaction depicts the final step in the industrial hydration of ethene. Ethyl hydrogen sulfate is hydrolyzed by water to yield ethanol and regenerate sulfuric acid.

Formula:

Not strictly necessary, but mathematically it is the addition of \(\text{H}_2\text{O}\) elements over the entire process.

Solution:

  • The reactant reacts with water (\(\text{H}_2\text{O}\)) and incorporates the elements of water (H and OH) into the final organic framework (if we consider the overall mechanism from ethene).


  • In chemical terms, treating the alkyl sulfate with water to replace the sulfate group with a hydroxyl group is technically hydrolysis, but in the context of the overall synthesis from alkenes, this step completes the hydration sequence.


Why other options are incorrect:

It is not reduction or oxidation as the oxidation states of the carbons do not change. It is not hydroxylation (which usually implies adding two -OH groups across a double bond via osmium tetroxide or cold permanganate).

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