Chemistry Alcohols & Phenols NUMS 2019
PMDC Verified Question 69 of 95
Phenol reacts with \(\text{CH}_3\text{COCl}\) to give
A
Acid
B
Ester
C
Aldehyde
D
Ketone
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Ester
Concept:

The reaction of an alcohol or a phenol with an acid chloride (acyl chloride) is an acylation reaction that yields an ester.

Formula:

$$ \text{C}_6\text{H}_5\text{OH} + \text{CH}_3\text{COCl} \longrightarrow \text{CH}_3\text{COOC}_6\text{H}_5 + \text{HCl} $$

Solution:

  • Phenol acts as a nucleophile, attacking the electrophilic carbonyl carbon of acetyl chloride (\(\text{CH}_3\text{COCl}\)).


  • The chloride ion is expelled as a leaving group.


  • The resulting functional group is an ester (phenyl acetate).


Why other options are incorrect:

Esters are strictly formed by the combination of an acyl group and an alkoxy/aryloxy group. Acid, aldehyde, and ketone functional groups do not match the product structure.

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