Chemistry Alcohols & Phenols PMDC 2020
PMDC Verified Question 61 of 95
IUPAC name of \(\text{C}_6\text{H}_8\text{O}(\text{CH}_3)_2\) is
A
2-Methyl-3-hexanone
B
2,6-Dimethyl cyclohexanone
C
3-Methyl cyclohexanone
D
4-Methy 1-3-hexanone
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: 2,6-Dimethyl cyclohexanone
Concept:

Determine the base ring from the formula. The parent saturated six-membered ring with a ketone is cyclohexanone (\(\text{C}_6\text{H}_{10}\text{O}\)).

Formula:

Not applicable to this conceptual question.

Solution:

  • The formula \(\text{C}_6\text{H}_8\text{O}(\text{CH}_3)_2\) implies two hydrogen atoms of cyclohexanone have been substituted by two methyl groups.


  • Based on common past-paper structural variants matching this formula and typical options, the methyls are situated adjacent to the ketone carbonyl carbon (positions 2 and 6) for maximum symmetry/stability in these test questions.


  • This gives 2,6-dimethylcyclohexanone.


Why other options are incorrect:

Option A and D are linear hexanones, which would have a different molecular formula (aliphatic ketones have formulas following \(\text{C}_n\text{H}_{2n}\text{O}\)). Option C only accounts for one methyl group, violating the provided formula.

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