Chemistry Alcohols & Phenols UHS 2022
PMDC Verified Question 39 of 95
When phenol reacts with formaldehyde, which of the following product is produced?
A
Adduct
B
Oxonium ion
C
Hydronium ion
D
Phenoxide ion
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Adduct
Concept:

The initial step in the formation of the polymer Bakelite involves an electrophilic substitution where formaldehyde adds to the phenol ring.

Formula:

Not applicable to this conceptual question.

Solution:

  • Phenol reacts with formaldehyde (HCHO) in the presence of dilute acid or alkali.


  • The initial product is ortho- and para-hydroxybenzyl alcohol.


  • Because this intermediate represents the direct addition of the two reactants without the loss of any small molecules initially, it is referred to as an adduct (specifically, saligenin).


Why other options are incorrect:

Oxonium and hydronium are positively charged oxygen intermediates/ions, not the stable isolable products of this step. Phenoxide ion is formed just by adding a base, not by reaction with formaldehyde.

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