Chemistry Alcohols & Phenols DUHS 2022
PMDC Verified Question 50 of 95
Benzyl alcohol \(\text{C}_6\text{H}_5\text{CH}_2\text{OH}\) is a:
A
Aromatic alcohol
B
Phenol
C
Aromatic ketone
D
Aliphatic alcohol
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Aromatic alcohol
Concept:

The classification between a phenol and an aromatic alcohol depends entirely on whether the hydroxyl (-OH) group is directly attached to the benzene ring or to an aliphatic side chain.

Formula:

Not applicable to this conceptual question.

Solution:

  • In benzyl alcohol (\(\text{C}_6\text{H}_5\text{CH}_2\text{OH}\)), the -OH group is attached to an \(\text{sp}^3\) hybridized methylene (\(-\text{CH}_2-\)) carbon.


  • Because it contains a benzene ring, it is aromatic. However, because the -OH is not directly on the ring, it behaves chemically like a primary aliphatic alcohol rather than a phenol.


  • Therefore, the most accurate composite classification is an aromatic alcohol.


Why other options are incorrect:

It is not a phenol because the -OH is not directly on the ring. It is not an aliphatic alcohol because it clearly contains an aromatic benzene ring. It is not a ketone as it lacks a C=O group.

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