Chemistry Alcohols & Phenols BUMHS 2022
PMDC Verified Question 53 of 95
Which of the following is Lucas reagent?
A
\(\text{AlCl}_3\)
B
\(\text{HCl}\)
C
\(\text{ZnCl}_2\)
D
Both B and C
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Both B and C
Concept:

The Lucas test utilizes a specific mixture to differentiate primary, secondary, and tertiary alcohols based on the rate of alkyl chloride formation.

Formula:

$$ \text{Lucas Reagent} = \text{Conc. HCl} + \text{Anhydrous ZnCl}_2 $$

Solution:

  • The reagent requires concentrated hydrochloric acid (HCl) as the halogen source and proton donor.


  • It requires anhydrous zinc chloride (\(\text{ZnCl}_2\)) as a Lewis acid catalyst to coordinate with the oxygen atom, weakening the C-O bond.


  • Therefore, Both B and C are required components of the Lucas reagent.


Why other options are incorrect:

HCl or \(\text{ZnCl}_2\) alone is insufficient to constitute the active diagnostic reagent. \(\text{AlCl}_3\) is used in Friedel-Crafts reactions, not the Lucas test.

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