Chemistry Alcohols & Phenols NUMS 2024
PMDC Verified Question 20 of 95
Bakelite is formed upon polymerization of
A
\(\text{Phenol} + \text{Formaldehyde}\)
B
\(\text{Phenol} + \text{Acetaldehyde}\)
C
\(\text{Benzene} + \text{Formaldehyde}\)
D
\(\text{Phenol} + \text{Acetone}\)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: \(\text{Phenol} + \text{Formaldehyde}\)
Concept:

Bakelite is the trade name for one of the earliest synthetic plastics, a phenol-formaldehyde resin formed via step-growth condensation polymerization.

Formula:

$$ \text{C}_6\text{H}_5\text{OH} + \text{HCHO} \xrightarrow{\text{OH}^- / \text{H}^+} \text{Polymer (Bakelite)} $$

Solution:

  • The necessary monomers to form the heavily cross-linked 3D structure of Bakelite are phenol and formaldehyde (methanal).


  • They initially react to form ortho- and para-hydroxymethylphenols, which subsequently condense (eliminating water) to form complex methylene bridges.


Why other options are incorrect:

Acetaldehyde, benzene, and acetone are not the constituent monomers for standard Bakelite resin. Acetone and phenol form Bisphenol A (BPA), not Bakelite.

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