Chemistry Aldehydes & Ketones MDCAT 2012
PMDC Verified Question 88 of 94
With acidified \( Na_2Cr_2O_7 \), what the product will be, when secondary alcohols are oxidized in same conditions?
A
Alkenes
B
Alkyl halides
C
Alkynes
D
Ketones
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Ketones
Concept:

The oxidation of alcohols depends on their substitution class (primary, secondary, or tertiary).

Solution:

  • Primary alcohols oxidize to aldehydes, and then further to carboxylic acids.


  • Secondary alcohols contain a \( >CH-OH \) group.


  • When treated with a strong oxidizing agent like acidified Sodium Dichromate (\( Na_2Cr_2O_7 \) / \( H_2SO_4 \)), secondary alcohols lose two hydrogen atoms to form a carbon-oxygen double bond, yielding a ketone.


Why other options are incorrect:

Alkenes are formed via dehydration, not oxidation. Alkyl halides require substitution with halogens. Alkynes require elimination of dihalides.

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