Chemistry Aldehydes & Ketones MDCAT 2017
PMDC Verified Question 67 of 94
Ethanal reacts with HCN to form cyanohydrin. It is an example of:
A
Nucleophilic addition
B
Electrophilic substitution
C
Electrophilic addition
D
Nucleophilic substitution
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Nucleophilic addition
Concept:

Carbonyl compounds (aldehydes and ketones) undergo reactions initiated by nucleophiles because the carbonyl carbon is electron-deficient (partially positive).

Solution:

  • In the reaction with HCN, the attacking species is the strong nucleophile \( CN^- \).


  • The \( CN^- \) attacks the electrophilic carbonyl carbon of ethanal, adding itself to the molecule.


  • The \( \pi \) bond breaks and the oxygen accepts a proton, creating a single tetrahedral product. Because two molecules merge into one without any byproducts leaving, it is strictly an addition reaction.


  • Thus, it is a Nucleophilic Addition reaction.


Why other options are incorrect:

Substitution implies replacing an atom, but here no atoms are lost. Electrophilic addition is characteristic of alkenes where the initial attack is by an electrophile (like \( H^+ \)), not a nucleophile.

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