Chemistry Aldehydes & Ketones ETEA 2016
PMDC Verified Question 78 of 94
The compound Aldehyde hydrazine is:
A
\( R-CH=N-NH_2 \)
B
\( R_2C=N-NH_2 \)
C
\( R-CH=N-O-NH_2 \)
D
\( R-CH=O-N=NH \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: \( R-CH=N-NH_2 \)
Concept:

When hydrazine (\( H_2N-NH_2 \)) reacts with a carbonyl compound, water is eliminated to form a hydrazone.

Solution:

  • An aldehyde has the general structure \( R-CHO \).


  • Reacting it with hydrazine removes the oxygen from the aldehyde and two hydrogens from one of the nitrogens in hydrazine.


  • This forms a double bond between the aldehyde carbon and the nitrogen, resulting in the structure \( R-CH=N-NH_2 \).


  • While commonly called a hydrazone, the option representing the "aldehyde hydrazine" (hydrazone) is clearly A.


Why other options are incorrect:

Option B represents a ketone hydrazone (two R groups on the carbon). Options C and D are chemically nonsensical structures with incorrect valencies and bonding for this reaction.

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