Chemistry Aldehydes & Ketones DUHS 2022
PMDC Verified Question 35 of 94
Acetone gives:
A
Fehling solution test positive
B
Silver mirror test positive
C
Lucas test positive
D
Iodoform test positive
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Iodoform test positive
Concept:

Acetone (propanone) is a ketone and exhibits chemical properties distinct from both aldehydes and alcohols.

Solution:

  • Acetone has the structure \( CH_3-CO-CH_3 \).


  • Because it contains a methyl group directly bonded to the carbonyl carbon (\( CH_3-CO- \)), it readily undergoes the haloform reaction.


  • When treated with iodine and base, it yields a yellow precipitate of iodoform (\( CHI_3 \)), making it Iodoform test positive.


Why other options are incorrect:

Ketones strongly resist oxidation and will not give a positive Fehling's (A) or Silver Mirror (B) test. The Lucas test (C) is strictly for differentiating primary, secondary, and tertiary alcohols, not ketones.

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