Chemistry Aldehydes & Ketones ETEA 2023
PMDC Verified Question 19 of 94
The reaction of aldehydes and ketones to alkanes in the presence of Zinc amalgam and \( HCl \) is called:
A
Clemmenson reduction
B
Williamson's synthesis
C
Wolf-Kishner reduction
D
Dow process
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Clemmenson reduction
Concept:

The complete deoxygenation of a carbonyl group (\( C=O \)) down to a methylene group (\( -CH_2- \)) is achieved via specific name reactions depending on the pH environment.

Formula:

$$ >C=O + 4[H] \xrightarrow{Zn-Hg \ / \ HCl} >CH_2 + H_2O $$

Solution:

  • The reagents Zinc amalgam (\( Zn-Hg \)) and concentrated Hydrochloric acid (\( HCl \)) create a strongly acidic reducing environment.


  • This specific reagent combination and reaction pathway is definitively named the Clemmensen reduction.


Why other options are incorrect:

The Wolff-Kishner reduction achieves the exact same transformation but uses basic conditions (Hydrazine / \( KOH \)). Williamson's synthesis is used to make ethers. Dow process is the industrial preparation of phenol from chlorobenzene.

Quality & Fidelity Assurance: Every question on BeambePrep is rigorously curated against the official PMDC syllabus with zero filler, zero out-of-syllabus content, and zero typos. When an authentic past paper originally contained a historical mistake or ambiguity from the examining board (such as UHS or NUMS), BeambePrep faithfully reflects the original paper while detailing the nuance and scientific consensus in the autopsy above.

Want to solve full-length papers under timed exam conditions?

Practice with zero-scroll lockdown sprints, dynamic latency zone timers, live peer selection telemetry, and the automated Amber mistake recovery loop.