Chemistry Atomic Structure MDCAT 2018
PMDC Verified Question 79 of 95
Which is the correct electronic configuration of chromium (24Cr)?
A
\( 1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^2, 3d^4 \)
B
\( 1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^1, 3d^5 \)
C
\( 1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 3d^6 \)
D
\( 1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^2, 3d^6 \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: \( 1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^1, 3d^5 \)
Concept: Half-filled (\(d^5\)) and fully-filled (\(d^{10}\)) subshells offer extra thermodynamic exchange energy and spherical symmetry, making them exceptionally stable.

Formula: None required.

Solution:
  • Chromium has an atomic number \( Z = 24 \).
  • The expected Aufbau configuration is \( [Ar] 4s^2 3d^4 \).
  • However, to achieve the highly stable half-filled \(d\)-subshell, one electron is promoted from the \(4s\) orbital to the \(3d\) orbital.
  • The actual configuration is anomalous: \( 1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^1, 3d^5 \).


Why other options are incorrect: Option A assumes rigid adherence to Aufbau without accounting for half-filled stability. Options C and D have incorrect total electron counts.

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