Chemistry Atomic Structure PMC 2021
PMDC Verified Question 70 of 95
Each electron in an atom must have its own unique set of quantum number is a statement of ____
A
Aufbau principle
B
Hund's rule
C
Pauli exclusion principle
D
None of these
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: Pauli exclusion principle
Concept: The foundational rules of quantum mechanics govern how electrons populate atoms to prevent the physical impossibility of two identical fermions occupying the exact same space and state.

Formula: None required.

Solution:
  • The Pauli Exclusion Principle explicitly states that no two electrons in a single atom can have an identical set of all four quantum numbers (\(n, l, m, s\)).
  • Even if two electrons share the same orbital (meaning \(n, l\), and \(m\) are identical), they must have opposite spins (one \(s = +1/2\), the other \(s = -1/2\)).


Why other options are incorrect: The Aufbau principle dictates the order of energy filling (lowest energy first). Hund's rule dictates that electrons singly occupy degenerate orbitals before pairing up.

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