Chemistry Atomic Structure BUMHS 2023
PMDC Verified Question 36 of 95
Which statement about a \( 4d \) orbital is correct?
A
It is at a higher energy level than a 4p orbital but has the same shape
B
It is occupied by one electron in an isolated Zn atom
C
It can hold a maximum of 10 electrons
D
It has highest energy of orbitals with principal quantum number four
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: It can hold a maximum of 10 electrons
Concept: The electron capacity of an entire subshell is dictated by its azimuthal quantum number (\( l \)).

Formula: $$ \text{Max Electrons} = 2(2l + 1) $$

Solution:
  • Note on exact phrasing: The question asks about a "\( 4d \) orbital" but the correct answer treats it as a "\( 4d \) subshell". In strict quantum terms, a single spatial orbital holds 2 electrons. A subshell holds more. However, in standard high school testing, "orbital" is frequently used interchangeably with "subshell".
  • For a \( d \)-subshell, \( l = 2 \).
  • Number of degenerate orbitals = \( 2(2) + 1 = 5 \).
  • Since each orbital holds 2 electrons, the entire \( d \)-subshell holds a maximum of \( 5 \times 2 = 10 \) electrons.


Why other options are incorrect: A \( 4d \) orbital has a different shape (clover/double-dumbbell) than a \( 4p \) orbital (dumbbell). Zinc (\( Z=30 \)) only fills up to \( 3d^{10} \); its \( 4d \) is completely empty. The \( 4f \) orbital has a higher energy than \( 4d \) within the principal quantum number 4.

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