Chemistry Carboxylic Acids MDCAT 2017
PMDC Verified Question 73 of 94
Final product of hydrolysis of nitrile yield:
A
Ketone
B
Alcohol
C
Aldehyde
D
Carboxylic acid
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Carboxylic acid
Concept:

The complete hydrolysis (acidic or basic) of a nitrile cleaves the carbon-nitrogen triple bond and converts the functional group entirely into a carboxyl group.

Formula:

$$ \text{R-C}\equiv\text{N} \xrightarrow{2\text{H}_2\text{O}, \text{H}^+} \text{R-COOH} + \text{NH}_4^+ $$

Solution:

  • Hydrolysis of a nitrile proceeds in two stages: partial hydrolysis yields an amide (\( \text{R-CONH}_2 \)).


  • Further, complete hydrolysis breaks the amide bond, replacing nitrogen with oxygen, generating a carboxylic acid.


Why other options are incorrect:

Alcohols, aldehydes, and ketones have different oxidation states or skeletons and are not products of nitrile hydrolysis without subsequent redox reactions.

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