Chemistry Carboxylic Acids MDCAT 2018
PMDC Verified Question 69 of 94
\( \text{C}_2\text{H}_5\text{OH} + \text{CH}_3\text{COOH} \rightleftharpoons \text{CH}_3\text{COOC}_2\text{H}_5 + \text{H}_2\text{O} \)
Which of the following catalyst is used in the above reaction?
A
Pt
B
Ni
C
Pumice stone
D
Conc. \( \text{H}_2\text{SO}_4 \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Conc. \( \text{H}_2\text{SO}_4 \)
Concept:

The esterification of a carboxylic acid with an alcohol requires an acid catalyst to proceed at a functional rate and to drive the equilibrium forward by sequestering the formed water.

Formula:

$$ \text{Acid} + \text{Alcohol} \rightleftharpoons_2\text{SO}_4} \text{Ester} + \text{Water} $$

Solution:

  • Concentrated sulfuric acid (\( \text{H}_2\text{SO}_4 \)) acts as both a catalyst (providing protons) and a dehydrating agent.


  • By absorbing \( \text{H}_2\text{O} \), it shifts the reaction equilibrium toward the right, maximizing ester yield.


Why other options are incorrect:

Platinum (Pt) and Nickel (Ni) are hydrogenation/reduction catalysts. Pumice stone prevents bumping during boiling but possesses no catalytic properties for esterification.

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