Chemistry Carboxylic Acids PMC 2021
PMDC Verified Question 52 of 94
Which of the following catalyst is used for the preparation of acidic anhydrides?
A
\( \text{K}_2\text{Cr}_2\text{O}_7 \)
B
\( \text{P}_2\text{O}_5 \)
C
\( \text{H}^+ / \text{H}_2\text{O} \)
D
\( \text{H}_2\text{SO}_4 \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: \( \text{P}_2\text{O}_5 \)
Concept:

Acid anhydrides are literally formed by removing a water molecule (dehydration) from two molecules of a carboxylic acid. This requires a powerful, specialized dehydrating agent.

Formula:

$$ 2\text{R-COOH} \xrightarrow{\text{P}_2\text{O}_5, \Delta} (\text{R-CO})_2\text{O} + \text{H}_2\text{O} $$

Solution:

  • Phosphorus pentoxide (\( \text{P}_2\text{O}_5 \)) is one of the strongest dehydrating agents known in chemistry.


  • When heated with a carboxylic acid, it forcefully extracts \( \text{H}_2\text{O} \), chemically locking the two acid remnants into an anhydride linkage.


Why other options are incorrect:

\( \text{H}_2\text{SO}_4 \) is a dehydrating agent, but it is typically used for esterification or dehydrating alcohols to alkenes. \( \text{P}_2\text{O}_5 \) is required for the much more difficult dehydration of acids to anhydrides.

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