Chemistry Carboxylic Acids UHS 2022
PMDC Verified Question 42 of 94
If carboxylic acid and ketone groups \( >\text{C=O} \) are present in a chain then final name will be given as:
A
Oxo, oic acid
B
One, oic acid
C
Both A and B
D
None of these
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Oxo, oic acid
Concept:

According to IUPAC priority rules, the carboxylic acid group (\( -\text{COOH} \)) holds the highest priority among common functional groups, thereby commanding the suffix of the molecule.

Solution:

  • Because the carboxylic acid governs the parent name, the molecule will end in the suffix "-oic acid".


  • The ketone group (\( >\text{C=O} \)) is consequently downgraded to a mere substituent.


  • As a prefix substituent, the ketone oxygen is denoted by the term "oxo-".


  • Therefore, the naming format is "...oxo...oic acid".


Why other options are incorrect:

The suffix "-one" is strictly reserved for when a ketone is the highest priority group in the molecule, which is never the case when an acid is present.

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