Chemistry Carboxylic Acids SZABMU 2024
PMDC Verified Question 8 of 94
On reacting acetic acid with baking soda a gas is evolved which turns lime water milky. Gas evolved is
A
\( \text{Cl}_2 \)
B
\( \text{NO}_2 \)
C
\( \text{H}_2 \)
D
\( \text{CO}_2 \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: \( \text{CO}_2 \)
Concept:

Carboxylic acids are sufficiently acidic to decompose carbonates and bicarbonates, liberating carbon dioxide gas in the process.

Formula:

$$ \text{CH}_3\text{COOH} + \text{NaHCO}_3 \longrightarrow \text{CH}_3\text{COONa} + \text{H}_2\text{O} + \text{CO}_2\uparrow $$
$$ \text{CO}_2 + \text{Ca(OH)}_2 \text{ (lime water)} \longrightarrow \text{CaCO}_3\downarrow \text{ (milky)} + \text{H}_2\text{O} $$

Solution:

  • Acetic acid reacts with baking soda (\( \text{NaHCO}_3 \)) via a standard acid-base neutralization.


  • The breakdown of the resulting carbonic acid rapidly evolves carbon dioxide (\( \text{CO}_2 \)) gas.


  • When \( \text{CO}_2 \) is bubbled through lime water (calcium hydroxide), it forms insoluble calcium carbonate, turning the solution milky.


Why other options are incorrect:

Hydrogen (\( \text{H}_2 \)) is evolved with active metals, not carbonates, and does not turn lime water milky. \( \text{Cl}_2 \) and \( \text{NO}_2 \) are entirely unrelated to this acid-base reaction.

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