Chemistry Chemical Bonding MDCAT 2013
PMDC Verified Question 97 of 102
According to Valence shell electron pair repulsion theory, the repulsive forces between the electron pairs of central atom of a molecule are in the order:
A
Lone pair-bond pair > Lone pair-Lone pair
B
Bond pair-Bond pair > Lone pair-Lone pair > Lone pair-Bond pair
C
Lone pair-Bond pair > Bond pair-Bond pair > Lone pair-Lone pair
D
Lone pair-Lone pair > Lone pair-Bond pair > Bond pair-Bond pair
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Lone pair-Lone pair > Lone pair-Bond pair > Bond pair-Bond pair
Concept:

The VSEPR theory states that electron pairs around a central atom repel each other, and lone pairs exert a stronger repulsive force than bond pairs because they are held closer to the central nucleus.

Formula:

$$ \text{Repulsion Order: LP-LP} > \text{LP-BP} > \text{BP-BP} $$

Solution:

  • Lone pairs (LP) occupy more space in the electron cloud because they are attracted to only one nucleus.


  • Bond pairs (BP) are stretched between two nuclei, making their electron cloud more concentrated and exerting less repulsion.


  • Therefore, two lone pairs repel each other the most, while two bond pairs repel each other the least.


Why other options are incorrect:

  • Option A, Option B, Option C: These options invert or scramble the correct descending order of repulsive strength defined by VSEPR theory.

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