Chemistry Chemical Bonding ETEA 2022
PMDC Verified Question 43 of 102
Identify the compound given below which has bond formed by overlapping of sp and p orbital:
A
\( \text{BeCl}_2 \)
B
\( \text{BF}_3 \)
C
\( \text{H}_2\text{O} \)
D
\( \text{NH}_3 \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: \( \text{BeCl}_2 \)
Concept:

Determine the hybridization of the central atom to see which one utilizes \( \text{sp} \) hybrid orbitals to bond with the unhybridized p-orbitals of a halogen.

Formula:

$$ \text{Steric Number (SN)} = 2 \implies \text{sp hybridization} $$

Solution:

  • Beryllium in \( \text{BeCl}_2 \) forms 2 single bonds with Chlorine and has 0 lone pairs.


  • A steric number of 2 means Be is \( \text{sp} \) hybridized.


  • Chlorine uses its unhybridized 3p orbital to bond. Thus, the bond is a direct \( \text{sp - p} \) overlap.


Why other options are incorrect:

  • Option B: Boron in \( \text{BF}_3 \) is \( \text{sp}^2 \) hybridized.
  • Option C & Option D: Oxygen in water and Nitrogen in ammonia are \( \text{sp}^3 \) hybridized (and hydrogen uses s-orbitals, not p-orbitals).

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