Chemistry Chemical Bonding ETEA 2023
PMDC Verified Question 29 of 102
Molecule having the highest bond energy (Experimentally) is:
A
HCl
B
HF
C
HBr
D
HI
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: HF
Concept:

Bond energy is inversely proportional to bond length. Shorter bonds are stronger because the nuclei are closer to the shared electron pair.

Formula:

$$ \text{Bond Energy} \propto \frac{1}{\text{Bond Length}} $$

Solution:

  • Fluorine is the smallest halogen atom. When it bonds with Hydrogen, the resulting H-F bond length is extremely short.


  • Because the bonding electrons are held very tightly and closely between the two nuclei, a massive amount of energy (approx. 567 kJ/mol) is required to break the bond.


  • As we go down the halogen group (Cl, Br, I), the atomic size increases, bond length increases, and bond energy rapidly decreases.


Why other options are incorrect:

  • Option A, Option C, Option D: These molecules feature progressively larger halogens, resulting in longer, weaker bonds that are easier to break.

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