Chemistry Chemical Bonding NUMS 2024
PMDC Verified Question 19 of 102
Predict the highest bond energy of the following single bond:
A
C - H
B
C - N
C
C - O
D
C - C
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: C - H
Concept:

Bond energy is strongly dependent on bond length. Shorter bonds are generally stronger. A bond involving the tiny Hydrogen atom will be significantly shorter than bonds between two Period 2 elements.

Formula:

$$ \text{Bond Energy} \propto \frac{1}{\text{Bond Length}} $$

Solution:

  • Hydrogen is the smallest atom (only a 1s orbital). Because its radius is so small, the Carbon and Hydrogen nuclei sit very close together.


  • This short distance (approx. 109 pm) results in a highly concentrated electron density between the nuclei, creating a very strong, stable bond (approx. 413 kJ/mol).


  • Bonds like C-C, C-N, and C-O involve two larger atoms (Period 2), resulting in longer, slightly weaker single bonds (ranging from 300 to 350 kJ/mol).


Why other options are incorrect:

  • Option B, Option C, Option D: All feature longer internuclear distances compared to a C-H bond, resulting in lower bond dissociation energies.

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