Chemistry Electrochemistry SET 2019
PMDC Verified Question 47 of 73
The value of oxidation number of chlorine in \( HClO_3 \) is:
A
+7
B
+5
C
-1
D
+3
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: +5
Concept:

For a neutral molecule, the sum of the oxidation states of all the constituent atoms must equal exactly zero.

Formula:

$$(+1) + x + 3(-2) = 0$$

Solution:

  • Hydrogen (H) generally has an oxidation state of \( +1 \).


  • Oxygen (O) is \( -2 \).


  • Let \( x \) be the oxidation state of Chlorine (Cl).


  • Set up the equation: \( 1 + x - 6 = 0 \).


  • Solve for \( x \): \( x - 5 = 0 \implies x = +5 \).


Why other options are incorrect:

Chlorine shows \( -1 \) in hydrochloric acid (\( HCl \)), \( +3 \) in chlorous acid (\( HClO_2 \)), and \( +7 \) in perchloric acid (\( HClO_4 \)).

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