Chemistry Electrochemistry MDCAT 2019
PMDC Verified Question 55 of 73
Aqueous solutions of Iodine and Sodium hydroxide were mixed in a round bottom flask at 70°C. Following chemical reaction was carried out:

\( 3I_2 + 6NaOH \rightarrow NaIO_3 + 5NaI + 3H_2O \)

This reaction is termed as:
A
Free radical reaction
B
Precipitation reaction
C
Substitution reaction
D
Redox reaction
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Redox reaction
Concept:

A disproportionation reaction is a specific type of redox reaction where the exact same element is simultaneously oxidized and reduced.

Solution:

  • Look at the oxidation state of Iodine (I) on the reactant side: \( I_2 \) is in its elemental state, so its oxidation number is \( 0 \).


  • On the product side, Iodine exists in two distinct compounds.


  • In Sodium Iodate (\( NaIO_3 \)): \( +1 + x + 3(-2) = 0 \implies x = +5 \) (Oxidation).


  • In Sodium Iodide (\( NaI \)): \( +1 + x = 0 \implies x = -1 \) (Reduction).


  • Because Iodine is both oxidized and reduced simultaneously, this is definitively a redox reaction.


Why other options are incorrect:

There is no insoluble solid formed (so not precipitation). There are no free radicals involved. It is an internal electron transfer, not a simple physical substitution.

Quality & Fidelity Assurance: Every question on BeambePrep is rigorously curated against the official PMDC syllabus with zero filler, zero out-of-syllabus content, and zero typos. When an authentic past paper originally contained a historical mistake or ambiguity from the examining board (such as UHS or NUMS), BeambePrep faithfully reflects the original paper while detailing the nuance and scientific consensus in the autopsy above.

Want to solve full-length papers under timed exam conditions?

Practice with zero-scroll lockdown sprints, dynamic latency zone timers, live peer selection telemetry, and the automated Amber mistake recovery loop.