Chemistry Electrochemistry PMC 2021
PMDC Verified Question 42 of 73
Which of the following is feasible reaction?
A
\( Pb + SnO \rightarrow PbO + Sn \)
B
\( Pb + Zn \rightarrow PbO + Zn \)
C
\( Zn + HCl \rightarrow ZnCl_2 + H_2 \)
D
\( 2Ag + 2HCl \rightarrow 2AgCl + H_2 \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: \( Zn + HCl \rightarrow ZnCl_2 + H_2 \)
Concept:

A single displacement reaction between a metal and an acid is feasible if the metal has a negative standard reduction potential (placing it above Hydrogen in the electrochemical series).

Solution:

  • Zinc (Zn) has a standard reduction potential of \( -0.76 \text{ V} \).


  • Because it is "above" Hydrogen (\( 0.00 \text{ V} \)), it acts as a stronger reducing agent.


  • Zinc will spontaneously donate electrons to the \( H^+ \) ions in Hydrochloric Acid, dissolving into \( ZnCl_2 \) and liberating \( H_2 \) gas. This makes option C highly feasible.


Why other options are incorrect:

Silver (Ag) in option D is a coinage metal situated below Hydrogen (positive reduction potential); it cannot displace Hydrogen from acids. Options A and B are thermodynamically non-spontaneous based on their relative reduction potentials.

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