Chemistry Electrochemistry SZABMU 2022
PMDC Verified Question 27 of 73
Which statement correctly describes the term Standard Electrode potential?
A
It is the electrode potential determined at room temperature and pressure
B
It is the electrode potential determined under standard condition using Hydrogen Electrode as the other electrode
C
It is the electrode potential of an element and its solution compare to zinc electrode
D
It is the potential which is measured when two half cells are connected
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: It is the electrode potential determined under standard condition using Hydrogen Electrode as the other electrode
Concept:

Single electrode potentials cannot be measured in isolation; they must be measured as a potential difference against a universally agreed-upon standard reference.

Solution:

  • The scientific community defines the Standard Hydrogen Electrode (SHE) as the ultimate reference point (assigned \( 0.00 \text{ V} \)).


  • The term "Standard Electrode Potential" (\( E^\circ \)) specifically means coupling the target half-cell (at standard conditions: \( 1 \text{ M} \) concentration, \( 1 \text{ atm} \) pressure, \( 298 \text{ K} \)) against the SHE and recording the voltage on a voltmeter.


Why other options are incorrect:

Option A mentions temperature and pressure but neglects the critical requirement of a reference electrode. Option C incorrectly suggests Zinc is the universal reference. Option D is simply the definition of cell potential, not a standard single electrode potential.

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