Chemistry Electrochemistry BUMHS 2024
PMDC Verified Question 15 of 73
What change in oxidation number of Cu takes place in the following reaction?

\( Cu + 4HNO_3 \rightarrow Cu(NO_3)_2 + 2NO_2 + 2H_2O \)
A
0 to -1
B
0 to +2
C
0 to -2
D
0 to +1
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: 0 to +2
Concept:

Track the oxidation state of the metal as it transitions from a free element into an ionic compound.

Solution:

  • On the reactant side, Copper (Cu) is in its elemental, uncombined state. By rule, its oxidation number is \( 0 \).


  • On the product side, Copper is part of the ionic compound Copper(II) nitrate, \( Cu(NO_3)_2 \).


  • The nitrate polyatomic ion (\( NO_3^- \)) carries a fixed charge of \( -1 \).


  • To balance two nitrate ions (a total of \( -2 \) charge), the single Copper atom must carry an oxidation state of \( +2 \).


  • Therefore, the oxidation number changes from \( 0 \) to \( +2 \).


Why other options are incorrect:

Copper very rarely exhibits a \( -1 \) or \( -2 \) state (it is a metal and prefers to lose electrons). While \( +1 \) is possible (Cu2O), the formula here demands \( +2 \).

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