Chemistry Electrochemistry NUMS 2024
PMDC Verified Question 18 of 73
Placing a rod of iron metal in a solution of \( CuSO_4 \):
A
Cu will be deposited
B
Fe is precipitated out
C
Cu and Fe both dissolve
D
No reaction taken place
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Cu will be deposited
Concept:

A single displacement redox reaction occurs when a more reactive solid metal is placed into a solution containing ions of a less reactive metal.

Solution:

  • Look at the electrochemical series. Iron (Fe) has a reduction potential of \( -0.44 \text{ V} \), while Copper (Cu) has a reduction potential of \( +0.34 \text{ V} \).


  • Because Iron is higher in the reactivity series (it is a stronger reducing agent), it wants to lose its electrons to the Copper ions.


  • The Iron rod will begin to dissolve (oxidize) into \( Fe^{+2} \) ions: \( Fe \rightarrow Fe^{+2} + 2e^- \).


  • The \( Cu^{+2} \) ions in the blue sulfate solution will accept those electrons and reduce into solid Copper metal: \( Cu^{+2} + 2e^- \rightarrow Cu \).


  • This solid Copper will be deposited on the iron rod and at the bottom of the beaker.


Why other options are incorrect:

Iron does not precipitate; it actively dissolves. Copper does not dissolve; it precipitates out of solution. The reaction is highly spontaneous, so "no reaction" is false.

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