Chemistry Equilibrium ETEA 2023
PMDC Verified Question 38 of 102
Haber's process is used for the synthesis of ammonia. The optimum temperature for the Haber process is:
A
\( 35 - 50^{\circ}\text{C} \)
B
\( 130 - 150^{\circ}\text{C} \)
C
\( 400 - 450^{\circ}\text{C} \)
D
\( 500 - 600^{\circ}\text{C} \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: \( 400 - 450^{\circ}\text{C} \)
Concept:

The Haber-Bosch process requires a compromise temperature. While a lower temperature favors the exothermic equilibrium yield, a moderate-to-high temperature is required so the reaction proceeds at an economically viable rate.

Solution:

  • The synthesis of ammonia (\( \Delta H = -92.4 \text{ kJ/mol} \)) is exothermic, so Le Chatelier's principle suggests low temperatures maximize yield.


  • However, at very low temperatures, the kinetic energy is too low to break the strong \( \text{N}\equiv\text{N} \) triple bonds, making the reaction agonizingly slow.


  • Industrial chemists use an "optimum" compromise temperature of roughly \( 400 - 450^{\circ}\text{C} \), paired with an iron catalyst, to get a reasonable yield in a short amount of time.


Why other options are incorrect:

Temperatures below 150°C are too slow kinetically. Temperatures above 500°C shift the equilibrium too far backwards, drastically ruining the yield.

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