Chemistry Equilibrium NUMS 2023
PMDC Verified Question 48 of 102
By which of the following factors equilibrium state is attained earlier?
A
Temperature
B
Pressure
C
Concentration
D
Catalyst
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Catalyst
Concept:

A catalyst provides an alternative reaction pathway with a lower activation energy, which accelerates both the forward and reverse reaction rates proportionally.

Formula:

$$ \text{Rate} \propto e^{-E_a / RT} $$

Solution:

  • When activation energy (\( E_a \)) is lowered by a Catalyst, a much larger fraction of molecules possess enough kinetic energy to react.


  • Both the forward and backward rates spike simultaneously.


  • Because both opposing rates are faster, they intersect and balance each other out in a fraction of the time.


  • Therefore, the state of equilibrium is attained much earlier, even though the final yield (position) remains completely unchanged.


Why other options are incorrect:

While temperature and concentration changes can affect rates, they also shift the position of the equilibrium. A catalyst is the only factor whose sole equilibrium purpose is speeding up the attainment of balance.

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