Chemistry Equilibrium UHS 2024
PMDC Verified Question 3 of 102
Identify the correct option required for the maximum yield of ammonia in Haber's process:
A
High pressure low temperature continual removal of ammonia
B
Low pressure low temperature continual removal of ammonia
C
High pressure high temperature continual removal of ammonia
D
High pressure low temperature continual addition of ammonia
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: High pressure low temperature continual removal of ammonia
Concept:

Maximizing yield in an industrial reversible reaction requires manipulating pressure, temperature, and concentrations according to Le Chatelier's Principle.

Formula:

$$ \text{N}_{2(g)} + 3\text{H}_{2(g)} \rightleftharpoons 2\text{NH}_{3(g)} \quad \Delta H < 0 $$

Solution:

  • High Pressure: Shifts equilibrium right because there are fewer moles of gas on the product side (4 moles vs 2 moles).


  • Low Temperature: Shifts equilibrium right because the forward reaction is exothermic (releases heat).


  • Continual Removal: Dropping the concentration of \( \text{NH}_3 \) forces the system to constantly try and replace it, preventing equilibrium from ever halting the reaction.


  • Combining these three factors yields the absolute maximum amount of product.


Why other options are incorrect:

Low pressure favors reactants. High temperature favors reactants. Continual addition of ammonia would violently drive the reaction backwards.

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