Chemistry Equilibrium SZABMU 2024
PMDC Verified Question 12 of 102
Maximum yield of ammonia can be obtained by
A
Low temperature, high pressure
B
Low temperature, low pressure
C
High temperature, high pressure
D
High temperature, low pressure
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Low temperature, high pressure
Concept:

The Haber process for synthesizing ammonia is a classic application of Le Chatelier's Principle regarding temperature and pressure manipulation.

Formula:

$$ \text{N}_{2(g)} + 3\text{H}_{2(g)} \rightleftharpoons 2\text{NH}_{3(g)} \quad \Delta H = -92.4 \text{ kJ/mol} $$

Solution:

  • Temperature: The forward reaction is exothermic. Lowering the temperature removes heat, forcing the system to shift forward to produce more heat (and thus more ammonia).


  • Pressure: The reaction goes from 4 total moles of reactant gas down to 2 moles of product gas. Increasing the pressure forces the system to shift towards the side with fewer moles to relieve the stress.


  • Combining these, Low temperature and high pressure mathematically guarantee the highest theoretical yield.


Why other options are incorrect:

High temperature shifts the reaction backwards. Low pressure shifts the reaction backwards.

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