Chemistry Equilibrium ETEA 2024
PMDC Verified Question 17 of 102
Consider \( \text{N}_2 + 3\text{H}_{2(g)} \rightarrow 2\text{NH}_{3(g)} \quad \Delta H = -92.46 \text{ kJ/mol} \)
The optimum temperature, (\( ^{\circ}\text{C} \)) to produce ammonia is
A
0
B
450
C
5000
D
Constant temperature
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: 450
Concept:

The Haber-Bosch process requires an "optimum" compromise temperature to balance thermodynamic yield against kinetic speed.

Solution:

  • Thermodynamically, because the reaction is exothermic (negative \( \Delta H \)), low temperatures maximize the theoretical yield of ammonia.


  • Kinetically, low temperatures make the reaction far too slow to be industrially viable because the activation energy required to break the \( \text{N}\equiv\text{N} \) triple bond is massive.


  • Industrial chemists use a compromise temperature of exactly 450\( ^{\circ}\text{C} \) (with an iron catalyst). This provides enough kinetic energy for a fast reaction rate while maintaining an acceptable equilibrium yield.


Why other options are incorrect:

0\( ^{\circ}\text{C} \) is kinetically dead (reaction won't happen). 5000\( ^{\circ}\text{C} \) would shift the equilibrium totally backward, destroying the ammonia. "Constant" is not a numerical value.

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