PMDC Verified Question 79 of 83
Which one of the following pair of compounds is cis and trans isomers of each other?

CH3 CH3 (I) CH3 CH3 (II)
A
Pair showing 2-butene with same and opposite sided methyls
B
Pair of chain isomers
C
Pair of structural isomers
D
Pair of identical molecules
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Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Pair showing 2-butene with same and opposite sided methyls
Concept:

A cis-trans isomer pair must have the exact same connectivity (same IUPAC name excluding the prefix) but differ in spatial arrangement around a rigid bond, such as a \( \text{C}=\text{C} \) double bond.

Solution:

  • The correct pair must show one molecule with identical groups on the same side of the double bond (cis) and the other with identical groups on opposite sides (trans).


  • Option A represents the geometric isomers of 2-butene.


Why other options are incorrect:

Other pairs represent molecules that differ in connectivity (structural isomers) or lack the necessary conditions for geometric isomerism entirely.

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