PMDC Verified Question 77 of 83
The structural formula of 2,3,4-trimethylpentane is:
A
\( \text{H}_3\text{C--CH}(\text{CH}_3)\text{--CH}(\text{CH}_3)\text{--CH}(\text{CH}_3)\text{--CH}_3 \)
B
\( \text{H}_3\text{C--CH}_2\text{--C}(\text{CH}_3)_2\text{--CH}_2\text{--CH}_3 \)
C
\( \text{H}_3\text{C--C}(\text{CH}_3)_2\text{--CH}_2\text{--CH}_3 \)
D
\( \text{CH}_3\text{--CH}_2\text{--CH}(\text{CH}_3)\text{--C}(\text{CH}_3)_3 \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: \( \text{H}_3\text{C--CH}(\text{CH}_3)\text{--CH}(\text{CH}_3)\text{--CH}(\text{CH}_3)\text{--CH}_3 \)
Concept:

To write the structural formula from an IUPAC name, first identify the parent chain, then place substituents at the specified carbon numbers.

Solution:

  • Parent chain: "pentane" indicates a 5-carbon continuous chain (\( \text{C--C--C--C--C} \)).


  • Substituents: "2,3,4-trimethyl" indicates three separate methyl (\( \text{-CH}_3 \)) groups attached to carbons 2, 3, and 4.


  • Adding the correct number of hydrogens gives: \( \text{CH}_3\text{--CH}(\text{CH}_3)\text{--CH}(\text{CH}_3)\text{--CH}(\text{CH}_3)\text{--CH}_3 \).


  • This matches Option A.


Why other options are incorrect:

Option B is 3,3-dimethylpentane. Option C is 2,2-dimethylbutane. Option D represents a different heavily branched isomer.

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