Chemistry Gases NUMS 2022
PMDC Verified Question 45 of 65
How should the condition be changed to prevent the value of a given gas from expanding when its mass is increased?
A
Temperature is lowered & pressure is increased
B
Temperature is increased & pressure is lowered
C
Temperature & pressure both are lowered
D
Temperature & pressure both are increased
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Temperature is lowered & pressure is increased
Concept:

We need to counteract an expansion in volume. By analyzing the ideal gas law (\( PV = nRT \)), we can see how manipulating temperature and pressure affects volume.

Formula:

$$ V = \frac{nRT}{P} $$

Solution:

  • When mass (and thus moles, \( n \)) is increased, Volume (\( V \)) naturally wants to increase to accommodate the extra particles.


  • To prevent this expansion (keep \( V \) constant or force it down), we must look at the remaining variables: Temperature (\( T \)) and Pressure (\( P \)).


  • Since \( V \propto T \), lowering the temperature will decrease the volume.


  • Since \( V \propto \frac{1}{P} \), increasing the pressure will compress the gas, also decreasing the volume.


  • Applying both simultaneously (lowering temperature AND increasing pressure) strongly counteracts the expansion caused by adding mass.


Why other options are incorrect:

  • Option B: Both actions would cause massive expansion, worsening the issue.
  • Options C & D: These combinations have opposing effects on volume, making them less effective or completely ineffective at strictly preventing expansion.

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