Chemistry Hydrocarbons MDCAT 2010
PMDC Verified Question 65 of 65
Ethyne molecule is formed when two carbon atoms joined together to form a sigma bond only:
A
sp-s overlap
B
sp-sp overlap
C
\( \text{sp}^2-\text{sp}^2 \) overlap
D
2py-2py overlap
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: sp-sp overlap
Concept:

In alkynes (like ethyne), the carbon atoms are sp hybridized, featuring linear geometry and a triple bond consisting of one sigma (\( \sigma \)) bond and two pi (\( \pi \)) bonds.

Solution:

  • Each carbon in ethyne (\( \text{HC}\equiv\text{CH} \)) utilizes sp hybridization.


  • The primary sigma bond directly between the two carbon atoms is formed by the head-to-head overlap of an sp orbital from one carbon with an sp orbital from the other carbon.


Why other options are incorrect:

  • sp-s overlap forms the C-H sigma bonds in ethyne, not the C-C bond.


  • \( \text{sp}^2-\text{sp}^2 \) overlap is characteristic of the C-C double bond in alkenes like ethene.


  • 2py-2py (and 2pz-2pz) sideways overlaps form the pi (\( \pi \)) bonds, not the sigma bond.

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