Chemistry Hydrocarbons MDCAT 2019
PMDC Verified Question 37 of 65
Which of the following reactions is used for the production of alcohols on industrial scale?
A
Hydrohalogenation of alkenes
B
Hydroxylation of alkenes
C
Hydrogenation of alkenes
D
Hydration of alkenes
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Hydration of alkenes
Concept:

Industrial synthesis requires cheap, abundantly available precursors. Ethene from petroleum cracking and steam (water) fit this requirement perfectly.

Solution:

  • The direct hydration of alkenes (adding \( \text{H}_2\text{O} \) across a double bond) is the standard industrial method to synthesize large quantities of simple alcohols.


  • For example, reacting ethene gas with high-pressure steam in the presence of a phosphoric acid catalyst yields vast amounts of industrial ethanol.


Why other options are incorrect:

  • Hydrohalogenation adds HX, yielding alkyl halides, not alcohols.


  • Hydrogenation adds \( \text{H}_2 \), yielding alkanes.


  • Hydroxylation uses expensive reagents (like \( \text{KMnO}_4 \) or \( \text{OsO}_4 \)) to form diols, which is not feasible for bulk mono-alcohol synthesis.

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