Chemistry Industrial Chemistry PMDC Conceptual Practice
PMDC Verified Question 13 of 41
Which functional structural moiety in a dye molecule is primarily responsible for light absorption in the visible spectrum?
A
Auxochrome
B
Mordant
C
Substrate
D
Chromophore
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Chromophore
Concept:

According to Witt's color theory, the color of an organic dye arises from an unsaturated light-absorbing structural unit known as a chromophore.

Formula / Reaction:

$$\Delta E = h\nu = \frac{hc}{\lambda} \quad (\text{Absorption in } 400\text{--}700\text{ nm range})$$

Solution:

  • Chromophores possess conjugated \(\pi\)-electron systems (e.g., \(-\text{N}=\text{N}-\), \(>\text{C}=\text{O}\), \(-\text{NO}_2\)) where electronic energy gaps (\(\Delta E\)) correspond to visible photons.


Why other options are incorrect:

  • Auxochrome: An electron-donating or withdrawing group (e.g., \(-\text{OH}\), \(-\text{NH}_2\)) that intensifies color and shifts \(\lambda_{\text{max}}\), but cannot generate color alone.


  • Mordant: An inorganic polyvalent metal salt used to fix dyes to fibers.


  • Substrate: The textile fiber or material being dyed.

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