Chemistry Industrial Chemistry PMDC Conceptual Practice
PMDC Verified Question 27 of 41
Bakelite, an early industrial thermosetting resin, is produced by the condensation reaction of:
A
Phenol and sodium hydroxide
B
Phenol and concentrated sulfuric acid
C
Phenol and acetyl chloride
D
Phenol and formaldehyde
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Phenol and formaldehyde
Concept:

Bakelite (polyoxybenzylmethylenglycolanhydride) is a cross-linked phenolic resin prepared by the acid- or base-catalyzed condensation of phenol with formaldehyde.

Formula / Reaction:

$$\text{C}_6\text{H}_5\text{OH} + \text{HCHO} \xrightarrow{\text{Acid or Base}} \text{Novolac / Resole} \xrightarrow{\Delta, \text{ Cross-link}} \text{Bakelite (3D Network)}$$

Solution:

  • Electrophilic aromatic substitution of formaldehyde at the ortho and para positions of phenol yields hydroxymethylphenols.


  • Further thermal condensation forms methylene (\(-\text{CH}_2-\)) cross-links, producing a rigid, three-dimensional thermoset.


Why other options are incorrect:

  • Option A: Forms sodium phenoxide salt without polymer chain extension.


  • Option B: Sulfonates the aromatic ring to produce phenolsulfonic acids.


  • Option C: Esterifies phenol to yield phenyl acetate.

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