Chemistry Liquids MDCAT 2011
PMDC Verified Question 71 of 73
Boiling point of water is higher than petrol, because intermolecular forces in water are:
A
Weaker than petrol
B
Stronger than petrol
C
Same as in petrol
D
Negligible
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Stronger than petrol
Concept:

The boiling point is a direct measure of the thermal energy required to overcome intermolecular forces (IMFs) in a liquid.

Formula:

$$ \text{Boiling Point} \propto \text{Intermolecular Forces} $$

Solution:

  • Water (\( \text{H}_2\text{O} \)) contains extensive, strong hydrogen bonds between its molecules.


  • Petrol (a mixture of hydrocarbons like octane) is non-polar and relies exclusively on weak London dispersion forces.


  • Because hydrogen bonds are significantly stronger than London dispersion forces, water requires much more heat energy to vaporize.


Why other options are incorrect:

Stating the forces are "weaker" or "negligible" contradicts the high boiling point (\( 100^\circ\text{C} \)) of water compared to the highly volatile nature of petrol.

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