Chemistry Liquids SZABMU 2022
PMDC Verified Question 36 of 73
Ice floats on the surface of water due to:
A
Large bond length
B
Cubic structure of ice
C
Weak intermolecular forces
D
Empty spaces in the structure of ice
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Empty spaces in the structure of ice
Concept:

Buoyancy dictates that a less dense object will float in a denser fluid. The density of ice is lower than that of liquid water.

Formula:

$$ \text{Density} = \frac{\text{Mass}}{\text{Volume}} $$

Solution:

  • In the liquid phase, water molecules dynamically slide past each other, packing relatively closely together.


  • When freezing into ice, hydrogen bonds dictate a strict, hexagonal crystal lattice.


  • This lattice forces the molecules to sit further apart, creating permanent "empty spaces" or voids within the structure.


  • Because the volume increases by roughly 9% without a change in mass, the density drops, causing the ice to float.


Why other options are incorrect:

Ice has a hexagonal, not cubic, structure. The intermolecular forces are actually highly stable and rigid, not weak. The primary physical cause of the volume expansion is the geometrical empty spaces.

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