Chemistry Liquids ETEA 2022
PMDC Verified Question 41 of 73
In which of the following molecule hydrogen bond is not present?
A
\( \text{H}_2\text{O} \)
B
\( \text{HF} \)
C
\( \text{CH}_4 \)
D
\( \text{NH}_3 \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: \( \text{CH}_4 \)
Concept:

Hydrogen bonding requires a hydrogen atom covalently bonded to a highly electronegative atom (N, O, or F).

Formula:

Not applicable.

Solution:

  • \( \text{H}_2\text{O} \), \( \text{HF} \), and \( \text{NH}_3 \) all feature hydrogen covalently bonded to small, highly electronegative atoms, leaving the hydrogen intensely electron-deficient and capable of forming H-bonds.


  • In Methane (\( \text{CH}_4 \)), carbon and hydrogen have very similar electronegativities (2.5 and 2.1, respectively).


  • Because the bond is essentially non-polar, the hydrogen atoms do not carry a significant partial positive charge, meaning hydrogen bonding is entirely absent. Methane relies only on London dispersion forces.


Why other options are incorrect:

Water, hydrogen fluoride, and ammonia are the three classic textbook examples of molecules that strongly exhibit hydrogen bonding.

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