Chemistry Liquids DUHS 2022
PMDC Verified Question 44 of 73
The two crystals \( \text{NaNO}_3 \) & \( \text{CaCO}_3 \) are both trigonal they are:
A
Isomers
B
Polymorphs
C
Allotropes
D
Isomorphs
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Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Isomorphs
Concept:

Isomorphism occurs when two or more distinct chemical compounds crystallize in the exact same geometric crystal structure.

Formula:

Not applicable.

Solution:

  • Sodium nitrate (\( \text{NaNO}_3 \)) and Calcium carbonate (\( \text{CaCO}_3 \)) are two entirely different chemical compounds.


  • However, due to similar ionic radii ratios and identical atomic ratios (1:1:3), they arrange themselves into identical trigonal crystal lattices.


  • Compounds exhibiting this structural mimicry are termed "Isomorphs."


Why other options are incorrect:

Polymorphs refer to a single substance existing in multiple structural forms. Allotropes refer to elements (like Carbon as diamond or graphite). Isomers are molecules with the same chemical formula but different structural connectivity. (Note: The original source listed 'Isomorphs' as Option E, it has been mapped to Option D here for standard JSON compliance.)

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