Chemistry Liquids DUHS 2024
PMDC Verified Question 12 of 73
Which of the following liquids show maximum surface tension?
A
Water
B
Mercury
C
Ethyl alcohol
D
Chloroform
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Mercury
Concept:

Surface tension arises from the net inward cohesive forces pulling on molecules at the surface of a liquid. Stronger cohesive forces result in higher surface tension.

Formula:

$$ \gamma \propto \text{Cohesive Force Strength} $$

Solution:

  • Water and Ethyl alcohol rely on hydrogen bonding. Water has a high surface tension for a molecular liquid (approx 72 mN/m) due to its dense H-bond network.


  • Chloroform relies on weaker dipole-dipole forces.


  • Mercury (Hg), however, is a liquid metal. It is not held together by standard intermolecular forces, but by Metallic Bonding.


  • The electrostatic sea of delocalized electrons creates an incredibly powerful cohesive force between the mercury atoms, resulting in a massive surface tension (approx 485 mN/m), pulling it tightly into spherical beads.


Why other options are incorrect:

No molecular hydrogen bond (as in water or alcohol) can compete in strength with the pure metallic bonding found in liquid mercury.

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