Chemistry Reaction Kinetics ETEA 2024
PMDC Verified Question 11 of 80
A reaction is first order with respect to A and second order with respect to B, the rate equation is:
A
Rate = \( k[\text{A}] \)
B
Rate = \( k[\text{A}][\text{B}] \)
C
Rate = \( k[\text{A}]^2[\text{B}] \)
D
Rate = \( k[\text{A}][\text{B}]^2 \)
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Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Rate = \( k[\text{A}][\text{B}]^2 \)
Concept:

The experimental order of a reaction with respect to a specific reactant becomes the mathematical exponent for that reactant's concentration in the rate law.

Solution:

  • The problem explicitly states the reaction is "first order with respect to A". This means the concentration of A, \( [\text{A}] \), must have an exponent of 1.
  • It states it is "second order with respect to B". This means the concentration of B, \( [\text{B}] \), must have an exponent of 2.
  • Combining these into the standard rate equation format yields: Rate = \( k[\text{A}]^1[\text{B}]^2 \).


Why other options are incorrect:

Option B represents a reaction that is first order for both A and B. Option C represents a reaction that is second order for A and first order for B (the inverse of the question).

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