Chemistry S & P Block Elements MDCAT 2016
PMDC Verified Question 88 of 104
The ionic radius of fluoride ion is:
A
72 pm
B
136 pm
C
95 pm
D
157 pm
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: 136 pm
Concept:

When a non-metal gains an electron to form an anion, electron-electron repulsion increases within the valence shell. Because the nuclear charge remains the same, the electron cloud expands, making the anionic radius significantly larger than its parent neutral atom.

Solution:

  • The actual atomic size of a neutral Fluorine (F) atom is 72 pm.
  • When it gains one electron to form the Fluoride ion (\( \text{F}^- \)), the added repulsion causes the radius to expand.
  • According to standard textbook values, the ionic radius of \( \text{F}^- \) increases to 136 pm.


Why other options are incorrect:

  • Option A: 72 pm is the covalent radius of the neutral F atom.
  • Options C & D: These values correspond to the atomic/ionic radii of larger halogens or elements, not fluorine.

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