Chemistry S & P Block Elements ETEA 2019
PMDC Verified Question 76 of 104
Which oxides of "K" contain more oxygen than is normal oxide?
A
Peroxide
B
Super oxide
C
Both contain equal quantity
D
None of the above
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Super oxide
Concept:

Potassium (K) forms a normal oxide (\( \text{K}_2\text{O} \)), a peroxide (\( \text{K}_2\text{O}_2 \)), and a superoxide (\( \text{KO}_2 \)). The oxygen-to-metal ratio determines which contains "more" oxygen.

Solution:

  • Normal Oxide (\( \text{K}_2\text{O} \)): 2 Potassium atoms to 1 Oxygen atom. Ratio = 0.5 oxygen per K.
  • Peroxide (\( \text{K}_2\text{O}_2 \)): 2 Potassium atoms to 2 Oxygen atoms. Ratio = 1 oxygen per K.
  • Superoxide (\( \text{KO}_2 \)): 1 Potassium atom to 2 Oxygen atoms. Ratio = 2 oxygen per K.
  • Comparing the ratios, the superoxide molecule contains the highest proportion of oxygen relative to the metal. Potassium naturally favors forming the superoxide when burned in excess air.


Why other options are incorrect:

  • While peroxides contain more oxygen than normal oxides, superoxides contain even more than peroxides, making it the most correct answer for "more oxygen".

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